Lehmann played in two 50-over matches against the Lions at Metricon Stadium earlier this month, scoring 32 in the opening contest.
The Lions chased down the Cricket Australia XI in both matches with a scheduled third clash abandoned without a ball bowled.
Young leg-spinner Pope has been added for the first four-day clash between the two squads.
Pope, 20, claimed 10 wickets in eight matches for KFC BBL|09 Championship winners the Sydney Sixers, although did not feature in the tournament final.
The four-day clash begins on Saturday, 15 February at Blundstone Arena.
CRICKET AUSTRALIA XI SQUAD
Jake Lehmann (c) (South Australia)
Max Bryant (Queensland)
Xavier Crone (Victoria)
Brendan Doggett (Queensland)
Jack Edwards (New South Wales)
Ryan Hadley (New South Wales)
Caleb Jewell (Tasmania)
Mitch Perry (Victoria)
Lachlan Pfeiffer (Queensland)
Lloyd Pope (South Australia)
Jason Sangha (New South Wales)
Sam Whiteman (Western Australia)
Saturday, Feb 15 - Tuesday, Feb 18
Cricket Australia XI v England Lions
Blundstone Arena - from 10.30am AEDT